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Diseño web: Paula M. Esquivias

Excess enthalpies of ketones + diether at 298.15 K

Autores/Authors: Rey-Martínez, F.J.; Martin-Gil, J.
Revista/Journal: Thermochimica Acta 1988, 130, 375-379
Fecha Publicación/Publication Date: 05/08/1988
Impacto/Impact: JCR (1988): 0.584    CHEMISTRY, ANALYTICAL   Posición/Position: 30/41    Cuartil/Quartile: Q3    Tercil/Tertile: T3
DOI: 10.1016/0040-6031(88)87085-0

Resumen/Abstract:

The excess molar enthalpy HmE has been determined as a function of mole fraction x at atmospheric pressure and 298.15 K for several binary mixtures of the type ketones (symmetrical and asymmetrical) + diether (1-2 dimethoxyethane). The ketones were 2-pentanone, 2-hexanone, 2-heptanone, 2-octanone, 2-nonanone, 3-pentanone, 4-heptanone, 5-nonanone. For all mixtures the excess molar enthalpies are positive except for the systems 2-pentanone, 3-pentanone, and 2-hexanone with 1,-2-dimethoxyethane. The values of HEm increase as the aliphatic chain of the ketone molecule increases.

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